3-GLYCIDOXYPROPYLTRIMETHOXYSILANE
3-GLYCIDOXYPROPYLTRIMETHOXYSILANE
3-Glycidoxypropyltrimethoxysilane = GPTMS
CAS Number: 2530-83-8
EC Number: 219-784-2
Molecular Weight: 236.34
Molecular Formula: C9H20O5Si
(3-Glycidyloxypropyl)trimethoxysilane (GPTMS) is a bifunctional organosilane with three methoxy groups on one side and an epoxy ring on the other.
The methoxy groups bind well with glass substrates creating a 3D matrix.
The epoxy group is reactive with amides, alcohols, thiols and acids.
GPTMS is highly reactive in water and can be used as a linking agent between the surface of the silica and the polymeric matrix.
3-Glycidoxypropyltrimethoxysilane is a kind of coupling agent with epoxy group.
3-Glycidoxypropyltrimethoxysilane can be used as caulking glue or sealant of polysulfide and polyurethane, adhesive of epoxy resin, and also can be used in thermosetting resin of filling or reinforcement mode, glass fiber adhesive and thermoplastic resin of inorganic filler or glass reinforcement, etc.
Improve intensity properties of hard composite materials which use glass fiber roving as reinforcement.
Keep intensity at maximum point after humidity period.
Enhance electrical properties of epoxy resin-based sealants, packaging materials, and printed circuit boards.
3-Glycidoxypropyltrimethoxysilane is the result of improving the adhesiveness between fillers or between resin and matrix.
Enhance electrical properties of composite materials of inorganic filling, including nylon and polybutylene terephthalate.
Be effective to various fillers, matrix, clay, talc, aedelforsite, silica and quartz, or metals like aluminum, copper and iron.
3-Glycidoxypropyltrimethoxysilane can improve the solubility, dispersity and fluidity of adhesive when put GPTMS into the organic toner.
Application
Pre-treatment of carbon steel with 3-(Glycidoxypropyl)trimethoxysilane enhances the dry and wet adhesion while reducing the cathotic disbondment rate of an epoxy coating
GPTMS is widely used as a silica precursor.
GPTMS alone with tetraethylortosilicate (TEOS) can be blended with chitosan for use as a filler for polymeric scaffold for bone tissue engineering.
3-Glycidoxypropyltrimethoxysilane can also be coated on the surface of aluminium alloy to protect from corrosion.
GPTMS can used to functionalize (wrap) multi-walled carbon nanotubes (MWCNTs) which can be used as s a reinforcement in epoxy matrix nanocomposites.
Physicochemical Properties
-Colorless transparent liquid;
-Soluble in a variety of organic solvents;
-Easy to hydrolysis;
-Able for condensation to form polysiloxanes;
-Easy to polymerize in the presence of overheating, light and peroxide.
Uses
3-Glycidoxypropyltrimethoxysilane is an epoxy-functional silane, GPTMS is a clear, light straw liquid.
3-Glycidoxypropyltrimethoxysilane may be used as a coupling agent in polysulfide and polyurethane caulks and sealants, in mineral-filled or glass-reinforced thermosets and thermoplastics, and in glass roving size-binders.
3-Glycidoxypropyltrimethoxysilane is particularly employed as an adhesion-promoting additive in waterborne systems, e.g. improving the adhesion of acrylic latex sealants.
The use of GLYMO (3-glycidoxypropyltrimethoxysilane) as a coupling agent in mineral-filled plastics improves filler dispensability, reduces its sedimentation tendency and greatly lowers the resin’s viscosity.
In addition 3-glycidoxypropyltrimethoxysilane leads to higher filler loading and a marked increase in water (vapor) resistance as well as resistance to acids and bases.
As a component of adhesives and sealants 3-glycidoxypropyltrimethoxysilane improves both adhesion to the substrate and mechanical properties such as flexural strength, tensile strength and modulus of elasticity.
3-Glycidoxypropyltrimethoxysilane is primary used as chemical intermediate and as adhesion promoter in coatings.
3-Glycidoxypropyltrimethoxysilane is a kind of coupling agent with epoxy group.
It can be used as caulking glue or sealant of polysulfide and polyurethane and as adhesive of epoxy resin.
3-Glycidoxypropyltrimethoxysilane can enhance the electrical properties of epoxy resin-based sealants, packaging materials, and printed circuit boards.
It can also be used to improve the cohesiveness of caulking glue and sealant with water containing acrylic latex used in polyurethane and epoxy resin coatings.
It can improve the solubility, dispersity and fluidity of adhesive when put it into the organic toner.
3-Glycidoxypropyltrimethoxysilane is used as cross-linking agent and adhesion promoter in commercially-available silicone sealant products.
Applications:
3-Glycidoxypropyltrimethoxysilane may improve dry and wet strength in cured composites reinforced with glass fiber rovings.
Enhance wet electrical properties of epoxy-based encapsulate and packaging materials.
Eliminate the need for a separate primer in polysulfide and urethane sealants.
Improve adhesion in waterborne acrylic sealants and in urethane and epoxy coatings.
Application
3-Glycidoxypropyltrimethoxysilane is mainly used in unsaturated polyester composites to improve the mechanical properties, electrical properties and light transmission properties of the composites, especially to improve their performance in wet environment.
In wire and cable industry, when used to treat EPDM system stuffed by pottery clay and crosslinked by peroxide, GPTMS can improve consumption factor and specific inductance captance.
Used for 3-Glycidoxypropyltrimethoxysilanes copolymerization with monomers like vinyl acetate and acrylic acid or methacrylic, to form the polymers widely used in coatings, adhesives and sealants, providing excellent adhesion and durability.
3-Glycidoxypropyltrimethoxysilane is primary used as chemical intermediate and as adhesion promoter in coatings.
3-Glycidoxypropyltrimethoxysilane is a kind of coupling agent with epoxy group.
3-Glycidoxypropyltrimethoxysilane can be used as caulking glue or sealant of polysulfide and polyurethane and as adhesive of epoxy resin.
3-Glycidoxypropyltrimethoxysilane can enhance the electrical properties of epoxy resin-based sealants, packaging materials, and printed circuit boards.
3-Glycidoxypropyltrimethoxysilane can also be used to improve the cohesiveness of caulking glue and sealant with water containing acrylic latex used in polyurethane and epoxy resin coatings.
3-Glycidoxypropyltrimethoxysilane can improve the solubility, dispersity and fluidity of adhesive when put GPTMS into the organic toner.
3-Glycidoxypropyltrimethoxysilane is used as cross-linking agent and adhesion promoter in commercially-available silicone sealant products.
-GPTMS is used to improve the adhesion between the surface of organic material and inorganic material, for example, the treatment of the glass fabric in glass steel and the silicon stuffing in plastic, rubber, paint, coating, etc.
-GPTMS is used in adhesive to strengthen the adhesion.
-The suitable resin include epoxy, phenol aldehyde, melamine, polysulfide, polyamino ester, polystyrene, etc.
-Improve the adhesion between inorganic stuffing, base material and resins, hence improve the mechanical strength, electric property of composite material and high retention in wet state.
-As the surface treating agent of inorganic stuffing, widely used in pottery clay, talcum powder, silicon grey clay, white carbon black, silica, aluminum powder, iron powder, etc.
-As epoxy sealing agent to stuff silica, epoxy concrete remedy material or coating to stuff sand and epoxy mould material to stuff metal.
-Improve the adhesion of double-component epoxy sealing agent, acrylic acid latex, sealing agent, polyamino ester, epoxy coating.
CAS NO.:2530-83-8
Density(25°C),g/cm3：1.065-1.075
Boiling Point ：262°C
Flash Point：122 °C
Refractive Index(nD20):1.4260-1.4280
Appearance：Colorless transparent liquid.
Dissolvability: Be soluble in water, and a hydrolysis reaction will occur at the same time, during which will release methanol.
Be soluble in alcohol and acetone, and also be soluble in most of aliphatic esters in the case of normal usage under 5%.
Handling and Storage
Handling
Normal measures for preventive fire protection.
Storage
Keep container tightly closed in a dry and well-ventilated place.
Recommended storage temperature is 2-8 °C.
Fire-fighting measures
Flammable properties
Flash point: 135 °C (275 °F)-closed cup
Ignition temperature: 400 °C (752 °F)
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special protective equipment for fire-fighters
Wear self-contained breathing apparatus for fire-fighting if necessary.
GPTMS Applications：
-As epoxy coupling agent, 3-Glycidoxypropyltrimethoxysilane is used in polysulfide-based and metal-filled epoxide resinous material.
-Improve the adhesion between inorganic stuffing, substrate material and resin, accordingly improve electrical property of electronic material which is made of epoxy resin and wrappage.
-GPTMS can be widely used in multi-fillers and substrates such as clay, talcum, tricalcium silicate, silica, quartz, aluminum, copper and iron.
-Including quartz-filled epoxy sealants, grail-filled epoxy resin and concrete patching material or coating, toner of modeling kits, and improving the dispersivity, fluidity of adhesive.
-To avoid the need of independent primer in polysulfide and polyurethane sealant and sealing compounds.
-Improve the adhesion of double-component epoxy sealing agent, GPTMS is used in polyurethane adhesive and sealant, epoxy resin adhesives, enhanced thermosetting resin, glass fiber adhesive, thermoplastic resin for inorganic filler or glass reinforcement.
3-Glycidoxypropyltrimethoxysilane Usage
1.GPTMS is an epoxy-containing coupling agent for caulking and sealants of polysulfide and polyurethane.
3-Glycidoxypropyltrimethoxysilane is also used in epoxy resin adhesives, filled or reinforced thermosetting resins, glass fiber adhesives and Inorganic filled or glass reinforced thermoplastic resin, etc.
Improves the strength properties of hard composites reinforced with glass fiber rovings.
2.GPTMS can enhance the electrical properties of epoxy resin electronic sealants and packaging materials and printed circuit boards, and improve the adhesion between resin and matrix or filler.
3.Electrical properties of composite materials including inorganic-filled nylon and polybutylene terephthalate.
4.Effective for a wide range of fillers and substrates such as clay, talc, wollastonite, silica, quartz or aluminum, copper and iron.
5.Improved aqueous acrylic latex caulks and sealants based on adhesion in polyurethane and epoxy coatings;Improves the compatibility, dispersibility and fluidity of the adhesive in the toner.
3-Glycidoxypropyltrimethoxysilane Packaging and Shipping
Packing: 200kg/drum or according to the requirement of clients.
3-Glycidoxypropyltrimethoxysilane Storage
Keep in a dry place, in a sealed containers.
CFS-838, 3-Glycidoxypropyltrimethoxysilane is a primary epoxy functional silane with a rapid hydrolysable trimethoxy group.
3-Glycidoxypropyltrimethoxysilane can improve adhesion to inorganic materials such as fillers, dyes, metals, glass fibers.
Better wettability and superior adhesion will be achieved with the presence of CFS-838.
3-Glycidoxypropyltrimethoxysilane is the equivalent of Momentive Silquest A-187 or Dynasylan GLYMO.
3-Glycidoxypropyltrimethoxysilane can be also described as 3-(2,3-Epoxypropoxy)propyltrimethoxysilane.
CFS-838 can be used as an adhesion promoter or a primer in the coating and sealants industries.
3-Glycidoxypropyltrimethoxysilane can enhance anti-corrosion, so GPTMS is a mostly used silane in marine coatings system.
CFS-838 can be used for electronic encapsulation and electronic packaging.
3-Glycidoxypropyltrimethoxysilane can improve electrical properties of composites.
CFS-838 can act as a surface modifier of inorganic fillers and glass fiber, to improve the bonding performance between organic resins and inorganic substrates.
Suitable polymers include epoxy, urethane, acrylic and polysulfide polymers.
CFS-838 can be used as a tackifier in cables manufacturing, with higher EVA ratio.
CFS-838 can be used as a foundry resin additive and improve mechanical and chemical properties.
Synonym(s):
GLYMO, Glycidyl 3-(trimethoxysilyl)propyl ether, 3-(2,3-Epoxypropoxy)propyltrimethoxysilane
Empirical Formula (Hill Notation):
C9H20O5Si
Glass fiber or glass fabric composites:As a finish or a size ingredient
Foundry resins: As an additive to polyurethane resin
Paints and coatings: As an additive and primer for improving adhesion to the substrate, especially glass and metal.
Chemical Name: 3-Glycidoxypropyltrimethoxysilane /KH-560
CAS No:2530-83-8
Molecular Formula: C9H20O5Si
Molecular Weight: 236.3
CFS-838 should be stored in a cool, well-ventilated place, and avoid exposure to humidity.
CFS-838 should be stored in its original containers and used up as soon as possible after opening.
When stored in a strictly sealed and unopened container, CFS-838 has a shelf life of 12months.
Item: Standard
Appearance: Colorless transparent liquid
Assay: ≥98%
Specific Gravity at 25°C, g/cm3: 1.065-1.075
Refractive Index, ND20: 1.4260-1.4280
KH-560 is the first widely used coupling agent and has been used for 40 years.
One end of GPTMSs structure with reactive groups such as amino and vinyl, can react with epoxy, phenolic, polyester and other synthetic resin molecules.
The other end is alkoxy (such as methoxy, ethoxy etc.) or chlorine atoms which is connected with silicon.
These groups can be transformed into silanol in the hydrolysis in water solution or damp air.
And the formed silanol is able to react with surface hydroxyl of glass, minerals and inorganic filler.
Therefore, silane coupling agent is commonly used in silicate-filled epoxy, phenolic, polyester resin and other systems.
In addition, 3-Glycidoxypropyltrimethoxysilane can also be used for FRP production, in order to improve GPTMSs mechanical strength and resistance to wet environment.
The organic groups of the silane coupling agent are selective about the reaction of the synthetic resin.
Generally, these organic groups lack sufficient reactivity with synthetic resins such as polyethylene, polypropylene and polystyrene, and thus the coupling effect for them is poor.
In recent years, new varieties of silane coupling agents with better coupling for polyolefins have been developed, but are limited in cost and other properties and are not yet widely used.
Silane coupling agent is also known as silane treatment agent.
3-Glycidoxypropyltrimethoxysilanes general formula is Y (CH2) nSiX3.
Wherein n is an integer of 0 to 3; X is a hydrolyzable group such as chlorine, methoxy, ethoxy and acetoxy; Y is an organic functional group such as a vinyl, an amino, an epoxy group, a methacryloyloxy group and sulfydryl.
CAS No.: 2530-83-8
Chemical Name: 3-Glycidoxypropyltrimethoxysilane
Synonyms:
GLYMO;GOPTS;A 187;(3-GL;ycidyL;Y 4087;Z 6040;CG6720;DZ 6040;KBM 403
CBNumber: CB2194134
Molecular Formula: C9H20O5Si
Formula Weight: 236.34
The reactions of 3-glycidoxypropyltrimethoxysilane in a highly basic aqueous solution have been studied by multinuclear magnetic resonance and light scattering techniques.
The study has shown that in this peculiar chemical environment the alkoxy groups of 3-glycidoxypropyltrimethoxysilane undergo a fast hydrolysis and condensation which favor the formation of open hybrid silica cages.
The silica condensation reaches 90% at a short aging time but does not go to completion even after 9 days.
The highly basic conditions also slow down the opening of the epoxies which fully react only after several days of aging.
The epoxy opening generates different chemical species and several reaction pathways have been observed; in particular, the formation of polyethylene oxide chains, diols, termination of the organic chain by methyl ether groups and formation of dioxane species.
These reactions are slow and proceed gradually with aging; light scattering analysis has shown that clusters of dimensions lower than 20 nm are formed after two days of reactions, but their further growth is hindered by the highly basic conditions which limit full silica condensation and formation of organic chains.
CAS Number: 2530-83-8
Molecular Weight: 236.34
Beilstein/REAXYS Number: 4308125
EC Number: 219-784-2
MDL number: MFCD00005144
PubChem Substance ID: 24867573
NACRES: NA.23
Appearance: Colorless transparent liquid
Color(Pt-Co): ≤25
Molecular Weight: 236.3
Specific Gravity (ρ20°C, g/cm3): 1.055
Refractive Index (nD25): 1.427
Boiling Point (°C): 290
Flash Point (°C): 149
Purity (%): ≥97.0
The study of silanes and polymers with special functions is increasing and the development of materials from silane-based polymers follows this trend.
In this way, the hydrolysis of 3-Glycidoxypropyltrimethoxysilane (GPTMS) was studied as a function of the hydrolysis time in solutions with 50% of alcoholic solvents by infrared spectroscopy.
3-Glycidoxypropyltrimethoxysilane was verified that GPTMS was possible to analyze qualitatively and quantitatively the chemical reactions involving the hydrolysis / condensation of GPTMS and the main kinetics variations during the process.
The results suggest that up to 30 minutes of hydrolysis, the predominant reactions are hydrolysis of the alkoxy groups, with the generation of the Si-OH groups and alcohol, in this case methanol.
From 30 minutes, there is a large amount of silanols in the solution that tend to condense and form siloxane groups, which has this reaction accelerated from 60 minutes.
Already, from 70-80 minutes, the reactions tend to decrease the kinetics, due to the absence of silanols and the hydrolysis / condensation process.
2530-83-8
3-glycidoxypropyltrimethoxysilane
(3-Glycidoxypropyl)trimethoxysilane
3-Glycidyloxypropyltrimethoxysilane
Glymo
Silicone KBM 403
Silane A 187
Union carbide A-187
Silan A 187
Silane Z 6040
Silane-Y-4087
Glycidoxypropyltrimethoxysilane
Glycidyloxypropyltrimethoxysilane
NUCA 187
KBM 403
KBM 430
3-(Trimethoxysilyl)propyl glycidyl ether
Glycidyl 3-(trimethoxysilyl)propyl ether
trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane
gamma-Glycidoxypropyltrimethoxysilane
(3-Glycidyloxypropyl)trimethoxysilane
3-(2,3-Epoxypropoxy)propyltrimethoxysilane
DZ 6040
3-Glycidoxypropyltrimethoxysilane Applications
1.3-Glycidoxypropyltrimethoxysilane is a coupling agent containing epoxy group.
3-Glycidoxypropyltrimethoxysilane can be used in sealants and sealants of polysulfide and polyurethane, as well as in epoxy tree adhesives, filling or reinforcing thermosetting resins, glass fiber adhesives and thermoplastic resins for inorganic filling or glass reinforcing.
2.3-Glycidoxypropyltrimethoxysilane can improve the strength properties of hard composites reinforced by glass fiber roving.
3.3-Glycidoxypropyltrimethoxysilane can enhance the electrical properties of epoxy-based electronic sealants, packaging materials and printed circuit boards, and improve the bonding force between resin and matrix or filler.
4.The electrical properties of inorganic filled nylon and polybutylene terephthalate composites can be enhanced.
5.3-Glycidoxypropyltrimethoxysilane is effective for a wide range of fillers and substrates, such as clay, talc, wollastonite, silica, quartz or metals such as aluminium, copper and iron.
6.3-Glycidoxypropyltrimethoxysilane can improve the adhesion of waterborne acrylic latex sealant and sealant in the coatings based on polyurethane and epoxy resin.
7.In organic toners, the solubility, dispersibility and fluidity of adhesives are improved.
Density: 1.0±0.1 g/cm3
Boiling Point: 299.4±0.0 °C at 760 mmHg
Melting Point: -50°C
Molecular Formula: C9H20O5Si
Molecular Weight: 236.338
Flash Point: 81.9±22.2 °C
Exact Mass: 236.108002
PSA: 49.45000
LogP: 0.28
Vapour Pressure 0.0±0.6 mmHg at 25°C:
Index of Refraction: 1.436
Storage condition: 2-8°C
3-Glycidoxypropyltrimethoxysilane is the first widely used coupling agent and has been used for 40 years.
One end of GPTMSs structure with reactive groups such as amino and vinyl, can react with epoxy, phenolic, polyester and other synthetic resin molecules.
The other end is alkoxy (such as methoxy, ethoxy etc.) or chlorine atoms which is connected with silicon.
These groups can be transformed into silanol in the hydrolysis in water solution or damp air.
And the formed silanol is able to react with surface hydroxyl of glass, minerals and inorganic filler.
Therefore, silane coupling agent is commonly used in silicate-filled epoxy, phenolic, polyester resin and other systems.
In addition, 3-Glycidoxypropyltrimethoxysilane can also be used for FRP production, in order to improve GPTMSs mechanical strength and resistance to wet environment.
The organic groups of the silane coupling agent are selective about the reaction of the synthetic resin.
Generally, these organic groups lack sufficient reactivity with synthetic resins such as polyethylene, polypropylene and polystyrene, and thus the coupling effect for them is poor.
In recent years, new varieties of silane coupling agents with better coupling for polyolefins have been developed, but are limited in cost and other properties and are not yet widely used.
Silane, trimethoxy[3-(oxiranylmethoxy)propyl]-
Silane coupler KH-560
1-(Glycidyloxy)-3-(trimethoxysilyl)propane
A 187
[3-(2,3-Epoxypropoxy)propyl]trimethoxysilane
NSC 93590
Trimethoxy(3-(oxiran-2-ylmethoxy)propyl)silane
Y 4087
Z 6040
Silicone A 187
Silane, trimethoxy[(oxiranylmethoxy)propyl]-
trimethoxy[3-(oxiran-2-ylmethoxy)propyl]silane
(3-(Glycidyloxy)propyl)trimethoxysilane
((3-(Trimethoxysilyl)propoxy)methyl)oxirane
(3-(2,3-Epoxypropoxy)propyl)trimethoxysilane
Silane, [3-(2,3-epoxypropoxy)propyl]trimethoxy-
MFCD00005144
.gamma.-Glycidoxypropyltrimethoxysilane
[3-(Glycidyloxy)propyl]trimethoxysilane
(3- GLYCIDOXYPROPYL)TRIMETHOXYSILANE
[[3-(Trimethoxysilyl)propoxy]methyl]oxirane
DSSTox_CID_7489
3-Glycidoxypropyltrimethoxysilane is an epoxy-functional silane, GPTMS is a clear, light straw liquid.
3-Glycidoxypropyltrimethoxysilane may be used as a coupling agent in polysulfide and polyurethane caulks and sealants, in mineral-filled or glass-reinforced thermosets and thermoplastics, and in glass roving size-binders.
3-Glycidoxypropyltrimethoxysilane is particularly employed as an adhesion-promoting additive in waterborne systems, e.g. improving the adhesion of acrylic latex sealants.
3-Glycidoxypropyltrimethoxysilane is epoxy functional silane used as adhesion promoters in SPUR, urethane, epoxy, polysulfide, silicone, and acrylic caulks, coatings, sealants and adhesives.
Applications:
3-Glycidoxypropyltrimethoxysilane may improve dry and wet strength in cured composites reinforced with glass fiber rovings
Enhance wet electrical properties of epoxy-based encapsulate and packaging materials.
Eliminate the need for a separate primer in polysulfide and urethane sealants.
Improve adhesion in waterborne acrylic sealants and in urethane and epoxy coatings.
Chemical Properties
CAS Number: 2530-83-8
EINECS Number: 219-784-2
IUPAC Name: Trimethoxy[3-(2-oxiranylmethoxy)propyl]silane
InChI: 1S/C9H20O5Si/c1-10-15(11-2,12-3)6-4-5-13-7-9-8-14-9/h9H,4-8H2,1-3H3
InChIKey: BPSIOYPQMFLKFR-UHFFFAOYSA-N
Molar Mass: 236.34 g/mol
Molecular Formula: C9H20O5Si
Synonyms: γ-Glycidoxypropyltrimethoxysilane
3-Glycidoxypropyltrimethoxysilane is used for the manufacture of: machinery and vehicles, fabricated metal products, food products, textile, leather or fur, wood and wood products, pulp, paper and paper products, rubber products, plastic products, mineral products (e.g. plasters, cement), electrical, electronic and optical equipment and furniture.
Release to the environment of this substance can occur from industrial use: formulation of mixtures and in the production of articles.
Other release to the environment of this substance is likely to occur from: indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and outdoor use.
The use of 3-glycidoxypropyltrimethoxysilane as a coupling agent in mineral-filled plastics improves filler dispensability, reduces its sedimentation tendency and greatly lowers the resin’s viscosity.
In addition 3-Glycidoxypropyltrimethoxysilane leads to higher filler loading and a marked increase in water (vapor) resistance as well as resistance to acids and bases.
As a component of adhesives and sealants.
Silqon A187 improves both adhesion to the substrate and mechanical properties such as flexural strength, tensile strength and modulus of elasticity.
[.gamma.-(Glycidyloxy)propyl]trimethoxysilane
Silane, trimethoxy(3-(oxiranylmethoxy)propyl)-
DSSTox_RID_78469
DSSTox_GSID_27489
Silane, (3-(2,3-epoxypropoxy)propyl)trimethoxy-
Oxirane, 2-((3-(trimethoxysilyl)propoxy)methyl)-
Oxirane, 2-[[3-(trimethoxysilyl)propoxy]methyl]-
Silicone A-187
3-Glycidoxypropyltrimethoxysilane, 97%
CAS-2530-83-8
CCRIS 3044
EINECS 219-784-2
C9H20O5Si
BRN 4308125
AI3-52752
Dynasylan GLYMO
Trimethoxy-g-glycidoxypropylsilane
EINECS 247-194-5
GOPTS
3-Glycidoxypropyltrimethoxysilane (2530-83-8) is Liquid.
3-Glycidoxypropyltrimethoxysilane is also known as 3-2,3-Epoxypropoxy propyl trimethoxysilane and Glycidyl-3-trimethoxysilyl propyl ether.
3-Glycidoxypropyltrimethoxysilane is use in glass fiber, glass fabric composites, Foundry resins, polyurethane resin, Paints and coatings, additive and primer and Adhesion the substrate glass and metal Industry.
Storage: Keep container tightly closed.
Keep container in a cool, well-ventilated area.
Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Glycidoxypropyltrimethyoxysilane, gamma-
Prosil 5136
((2,3-Epoxypropoxy)propyl)trimethoxysilane
Dow corning Z-6040
gamma-GLYCIDOXYPROPYL TRIMETHOXY SILANE
ACMC-209gj1
EC 219-784-2
SCHEMBL27615
glycidoxypropyl-trimethoxysilane
SILANE, 3-(2,3-EPOXYPROPOXY)PROPYLTRIMETHOXY-
TYPICAL APPLICATIONS OF GPTMS
GPTMS is an essential ingredient in the products of many industries:
-Glass fiber/glass fabric composites: as a finish or a size ingredient
-Foundry resins: as an additive to polyurethane resins
-Sealants and adhesives: as a primer or additive
-Mineral filled composites: for pretreatment of fillers and pigments or as an additive to the polymer
-Paints and coatings: as an additive and as a primer for improving adhesion to the substrate, especially glass and metal
-Improved shelf life over aminosilanes in polyurethanes
Storage
Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature is 2-8 °C.
Fire-fighting measures
Flammable properties
Flash point: 135 °C (275 °F)-closed cup
Ignition temperature: 400 °C (752 °F)
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special protective equipment for fire-fighters
Wear self-contained breathing apparatus for fire-fighting if necessary.
Toxicological Information
Acute toxicity: LD50 Oral-rat-8,030 mg/kg
LD50 Dermal-rabbit-4,248 mg/kg
Irritation and corrosion:
Eyes-rabbit-Mild eye irritation
Chemical Properties
Colorless transparent liquid
Uses
Pre-treatment of carbon steel with 3-(Glycidoxypropyl)trimet?hoxysilane enhances the dry and wet adhesion while reducing the cathotic disbondment rate of an epoxy coating
Application
GPTMS is widely used as a silica precursor. GPTMS alone with tetraethylortosilicate (TEOS) can be blended with chitosan for use as a filler for polymeric scaffold for bone tissue engineering.
It can also be coated on the surface of aluminium alloy to protect from corrosion
GPTMS can used to functionalize (wrap) multi-walled carbon nanotubes (MWCNTs) which can be used as s a reinforcement in epoxy matrix nanocomposites.
Pre-treatment of carbon steel with 3-(Glycidoxypropyl)trimethoxysilane enhances the dry and wet adhesion while reducing the cathotic disbondment rate of an epoxy coating
Physicochemical Properties
Colorless transparent liquid;
Soluble in a variety of organic solvents;
Easy to hydrolysis;
Able for condensation to form polysiloxanes;
Easy to polymerize in the presence of overheating, light and peroxide.
3-Glycidoxypropyltrimethoxysilane is a primary epoxy functional silane with a rapid hydrolysable trimethoxy group.
3-Glycidoxypropyltrimethoxysilane can improve adhesion to inorganic materials such as fillers, dyes, metals, glass fibers.
3-Glycidoxypropyltrimethoxysilane helps for better wettability and superior adhesion
It is the equivalent of Momentive Silquest A-187 or Dynasylan GLYMO.
It can be also described as 3-(2,3-Epoxypropoxy)propyltrimethoxysilane
3-Glycidoxypropyltrimethoxysilane Preparation
Products And Raw materials
Raw materials
Silicon
Methanol
Important product effects that can be achieved through the use of GLYMO include:
-Improved mechanical properties, such as flexural strength, tensile strength, impact strength and modulus of elasticity
-Improved moisture and corrosion resistance
-Improved electrical properties, for example dielectric constant, volume resistivity
GLYMO can also improve such processing properties as:
-Filler dispersion
-Rheological behavior (i.e. Viscosity reduction) newtonian behavior
-Increased filler loading
-Non yellowing
CHEMBL2140162
DTXSID5027489
3-glycidoxypropyltrimethoxy silane
3-glycidoxypropyltrimethoxy-silane
trimethoxysilylpropylglycidyl-ether
(g-glycidoxypropyl)trimethoxysilane
3-glycidoxy propyl trimethoxysilane
NSC93590
(3-glycidoxypropyl)trimethoxy-silane
3-glycidoxy propyl trimethoxy silane
Tox21_201672
Tox21_303288
ANW-25691
CG6720
Other names: Silane, [3-(2,3-epoxypropoxy)propyl]trimethoxy-; γ-Glycidoxypropyltrimethoxysilane; (3-Glycidoxypropyl)trimethoxysilane
[γ-(Glycidyloxy)propyl]trimethoxysilane; [[3-(Trimethoxysilyl)propoxy]methyl]oxirane; [3-(Glycidyloxy)propyl]trimethoxysilane
[3-(2,3-Epoxypropoxy)propyl]trimethoxysilane; A 187; DZ 6040; Glycidoxypropyltrimethoxysilane; Glycidyl 3-(Trimethoxysilyl)propyl ether
Glycidyloxypropyltrimethoxysilane; KBM 403; KBM 430; Silan A 187; Silane A 187; Silane Z 6040; Silicone A 187; Silicone KBM 403; Y 4087
Z 6040; 1-(Glycidyloxy)-3-(Trimethoxysilyl)propane; NUCA 187; Silane-y-4087; Union carbide a-187; CG6720; Dow corning Z-6040
Dynasylan GLYMO; Glymo; Prosil 5136; Silane, 3(glycidoxy)propyl trimethoxy-; Oxirane, 2-((3-(trimethoxysilyl)propoxy)methyl)-
3-(Trimethoxysilyl)propyl glycidyl ether; NSC 93590
gamma-glycidoxypropyl-trimethoxysilane
NSC-93590
gamma-glycidyloxypropyltrimethoxysilane
.alpha.-Glycidoxypropyltrimethoxysilane
AKOS008901332
Glycidyl 3-Trimethoxysilylpropyl Ether
MCULE-4223229449
Silane, 3(glycidoxy)propyl trimethoxy-
(.gamma.-Glycidoxypropyl)trimethoxysilane
NCGC00164370-01
NCGC00164370-02
NCGC00257095-01
NCGC00259221-01
Silane,3-epoxypropoxy)propyl]trimethoxy-
25704-87-4
AS-14542
L534
WLN: T3OTJ B1O3-SI-O1&O1&O1
The epoxy group in 3-glycidoxypropyltrimethoxysilane (GPS) readily undergoes hydrolysis in acidic conditions to form a solution containing principally the vicinal diol or a reaction product between the vicinal diol and the silanol groups formed during the hydrolysis (an alkoxysilane).
Additional reaction products include alkene, enol, low concentrations of carbonyl compounds, intermolecular condensation products, e.g. ethers, and reaction products specific to the acid used to promote the hydrolysis of the alkoxysilane and epoxy groups.
On evaporation of acidified GPS solutions at room temperature, a polymerized form of GPS is produced.
This polymer is found to be readily oxidized on heating in air and from simulated outdoor weathering trials (SODW), but not when formed on silica powders from a 1-2 wt% solution to form a coating.
In the absence of silica, unreacted hydroxy groups are readily available for oxidation, a result that is consistent with the reported molecular structure of polymerized GPS.
A chemical structure of a molecule includes the arrangement of atoms and the chemical bonds that hold the atoms together.
The 3-glycidoxypropyltrimethoxysilane molecule contains a total of 35 bond(s) There are 15 non-H bond(s), 9 rotatable bond(s), 1 three-membered ring(s), 2 ether(s) (aliphatic) and 1 Oxirane(s).
The 2D chemical structure image of 3-glycidoxypropyltrimethoxysilane is also called skeletal formula, which is the standard notation for organic molecules.
The carbon atoms in the chemical structure of 3-glycidoxypropyltrimethoxysilane are implied to be located at the corner(s) and hydrogen atoms attached to carbon atoms are not indicated – each carbon atom is considered to be associated with enough hydrogen atoms to provide the carbon atom with four bonds.
The 3D chemical structure image of 3-glycidoxypropyltrimethoxysilane is based on the ball-and-stick model which displays both the three-dimensional position of the atoms and the bonds between them.
The radius of the spheres is therefore smaller than the rod lengths in order to provide a clearer view of the atoms and bonds throughout the chemical structure model of 3-glycidoxypropyltrimethoxysilane.
For a better understanding of the chemical structure, an interactive 3D visualization of 3-glycidoxypropyltrimethoxysilane is provided here.
The 3-glycidoxypropyltrimethoxysilane molecule shown in the visualization screen can be rotated interactively by keep clicking and moving the mouse button.
Mouse wheel zoom is available as well – the size of the 3-glycidoxypropyltrimethoxysilane molecule can be increased or decreased by scrolling the mouse wheel.
The information of the atoms, bonds, connectivity and coordinates included in the chemical structure of 3-glycidoxypropyltrimethoxysilane can easily be identified by this visualization.
By right-clicking the visualization screen, various other options are available including the visualization of van der Waals surface and exporting to a image file.
Epoxy functional trialkoxy silane
Component in aluminum metal bonding adhesives
Coupling agent for epoxy composites employed in electronic “chip” encapsulation
Component in abrasion resistant coatings for plastic optics
Used to prepare epoxy-containing hybrid organic-inorganic materials
Used in microparticle surface modification
Epoxy silane treated surfaces convert to hydrophilic-diols when exposed to moisture
3-Glycidoxypropyltrimethoxysilane Chemical Properties, Uses, Production
Silane Coupling Agents
3-Glycidoxypropyltrimethoxysilane is the first widely used coupling agent and has been used for 40 years.
One end of its structure with reactive groups such as amino and vinyl, can react with epoxy, phenolic, polyester and other synthetic resin molecules.
The other end is alkoxy (such as methoxy, ethoxy etc.) or chlorine atoms which is connected with silicon.
These groups can be transformed into silanol in the hydrolysis in water solution or damp air.
And the formed silanol is able to react with surface hydroxyl of glass, minerals and inorganic filler.
Therefore, silane coupling agent is commonly used in silicate-filled epoxy, phenolic, polyester resin and other systems.
In addition, it can also be used for FRP production, in order to improve its mechanical strength and resistance to wet environment.
The organic groups of the silane coupling agent are selective about the reaction of the synthetic resin.
Generally, these organic groups lack sufficient reactivity with synthetic resins such as polyethylene, polypropylene and polystyrene, and thus the coupling effect for them is poor.
In recent years, new varieties of silane coupling agents with better coupling for polyolefins have been developed, but are limited in cost and other properties and are not yet widely used.
Silane coupling agent is also known as silane treatment agent.
Its general formula is Y (CH2) nSiX3.
.gamma.-[(Glycidoxypropyl)trimethoxy]silane
DB-028513
CS-0132309
FT-0615768
G0210
ST51037264
(3-Glycidyloxypropyl)trimethoxysilane, >=98%
gamma-(2,3-epoxypropoxy)propyltrimethoxysilane
S09160
trimethoxy-[3-(2-oxiranylmethoxy)propyl]silane
[3-(2,3-epoxypropoxy)-propyl]-trimethoxysilane
97859-EP2305685A1
97859-EP2305686A1
Trimethoxy[3-(2-oxiranylmethoxy)propyl]silane #
A817773
(3-Glycidyloxypropyl)trimethoxysilane, >=97% (GC)
J-015924
Q27262482
4,4,4-trimethoxy-1-(oxiran-2-ylmethoxy)-4-silabutane
dow corning z-6040 epoxyfunctional silicone adhesive additive
Quality Level: 200
assay: ≥98%
form: liquid
refractive index: n20/D 1.429 (lit.)
bp: 120 °C/2 mmHg (lit.)
density: 1.07 g/mL at 25 °C (lit.)
SMILES string: CO[Si](CCCOCC1CO1)(OC)OC
InChI: 1S/C9H20O5Si/c1-10-15(11-2,12-3)6-4-5-13-7-9-8-14-9/h9H,4-8H2,1-3H3
InChI key: BPSIOYPQMFLKFR-UHFFFAOYSA-N